Gold-Catalyzed Reactions of Enynals with Alkenes for Synthesis Binaphthyl Derivatives.
J Org Chem
; 89(9): 6074-6084, 2024 May 03.
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| MEDLINE
| ID: mdl-38626391
ABSTRACT
A PPh3Au[B(C6F5)4]-catalyzed reaction of enynals and alkenes for the construction of binaphthyl derivatives was described. This transformation was achieved through o-Quinodimethane (o-QDM) intermediate's extended conjugated addition process. The reaction has the advantages of wide substrate scopes, mild reaction conditions, high efficiency, and good scalability.
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2024
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