Bispidine Based Hg(II) 1D Coordination Polymers of Helical Topology: Stability, Selective Adsorption and 1D to 2D Dimensionality Change Via SC-to-SC Transformation.
Chemistry
; 30(40): e202401464, 2024 Jul 16.
Article
en En
| MEDLINE
| ID: mdl-38738456
ABSTRACT
Bispidine based Hg(II) coordination polymers of helical topology CP-MeOH and CP-EtOH are almost isostructural (they mainly differ for the solvent included in their lattice and by a small % in unit cell parameters) but they differ for everything else i) their intrinsic stability, ii) their ability to adsorb solvents upon prior evacuation, iii) their accessible structural transformations. In particular, one of the two starting materials, once evacuated, is capable to adsorb methanol from atmospheres containing binary and ternary mixtures of volatile organic compounds (MeOH, CHCl3 and EtOH) under ambient conditions (25 °C, 1â
atm) and with a marked selectivity. The other one is not, but undergoes a 1D to 2D dimensionality change which can be monitored inâ
situ by SC-XRD through a SC-to-SC process.
Texto completo:
1
Banco de datos:
MEDLINE
Idioma:
En
Año:
2024
Tipo del documento:
Article