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Evaluation of gold adsorption on activated carbon from real cyanide and thiourea leachate solutions.
Romero, Hugo; Suarez, Claudio; Salazar, Nelson; Zambrano, Cristhian; Lapo, Byron.
  • Romero H; Technical University of Machala, Chemical Engineering School, Electroanalytical Applications and Bioenergy Research Group, Machala, Postcode 070102, Ecuador.
  • Suarez C; Technical University of Machala, Chemical Engineering School, BIOeng Group, Machala, Postcode 070102, Ecuador.
  • Salazar N; Authievre Chemical Research Consulting Inc, Queen Street East, Toronto, G8-3017, Canada.
  • Zambrano C; Technical University of Machala, Chemical Engineering School, BIOeng Group, Machala, Postcode 070102, Ecuador.
  • Lapo B; Technical University of Machala, Chemical Engineering School, Electroanalytical Applications and Bioenergy Research Group, Machala, Postcode 070102, Ecuador.
Heliyon ; 10(11): e31606, 2024 Jun 15.
Article en En | MEDLINE | ID: mdl-38841478
ABSTRACT
The recovery of gold by adsorption using activated carbon from sodium cyanide and thiourea leached solutions are reported in this study. The leached solutions were obtained under real operating conditions from the beneficiation plant "Paz Borja", Machala-Ecuador. Calgon Carbon DG-11 6X12 type, widely used in the local metallurgical industry was used as adsorbent material. The operational parameters varied during the adsorption process experiments included the concentration of leaching agent, agitation speed, dose of activated carbon and initial concentration of gold. The control parameters included density, percentage of solid, pH, temperature, and solution potential. The obtained results were adjusted to mass transfer model by diffusion through the interface and the Freundlich model for the equilibrium isotherms. The analysis of the results indicates a higher adsorption rate of the gold di-cyanide complex on activated carbon compared to gold-thiourea complexes.
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