Synthesis and Photovoltaic Performance of ß-Amino-Substituted Porphyrin Derivatives.
Int J Mol Sci
; 25(11)2024 May 29.
Article
en En
| MEDLINE
| ID: mdl-38892167
ABSTRACT
New ß-amino-substituted porphyrin derivatives bearing carboxy groups were synthesized and their performance as sensitizers in dye-sensitized solar cells (DSSC) was evaluated. The new compounds were obtained in good yields (63-74%) through nucleophilic aromatic substitution reactions with 3-sulfanyl- and 4-sulfanylbenzoic acids. Although the electrochemical studies indicated suitable HOMO and LUMO energy levels for use in DSSC, the devices fabricated with these compounds revealed a low power conversion efficiency (PCE) that is primarily due to the low open-circuit voltage (Voc) and short-circuit current density (Jsc) values.
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MEDLINE
Asunto principal:
Porfirinas
/
Energía Solar
Idioma:
En
Año:
2024
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Article