Visible-Light-Activated Heteroaryl Azoswitches: Toward a More Colorful Future.
J Am Chem Soc
; 146(29): 19609-19620, 2024 Jul 24.
Article
en En
| MEDLINE
| ID: mdl-38991225
ABSTRACT
Azobenzenes (Ph-NâN-Ph) are known as the most widely studied molecular photoswitches, and the recent rise of azoheteroarenes (Het-NâN-Ph or Het-NâN-Het) offers great opportunities to advance this already mature field. A common limitation is that azo-switches generally require harmful UV light for activation, which hinders their application across various fields. Despite great efforts in developing visible-light azobenzenes over the past few decades, the potential of visible-light heteroaryl azoswitches remains largely unexplored. This Perspective summarizes the state-of-the-art advancements in visible-light heteroaryl azoswitches, covering molecular design strategies, the structure-property relationship, and potential applications. We highlight the distinctive advantages of azoheteroarenes over azobenzenes in the research and development of visible-light switches. Furthermore, we discuss the opportunities and challenges in this emerging field and propose potential solutions to address crucial issues such as spectral red-shift and thermal half-life. Through this Perspective paper, we aim to provide inspiration for further exploration in this field, in anticipation of the growing prosperity and bright future of visible-light azoheteroarene photoswitches.
Texto completo:
1
Banco de datos:
MEDLINE
Idioma:
En
Año:
2024
Tipo del documento:
Article