Strained silacycles in organic synthesis: a new reagent for the enantioselective allylation of aldehydes.
J Am Chem Soc
; 124(27): 7920-1, 2002 Jul 10.
Article
em En
| MEDLINE
| ID: mdl-12095334
ABSTRACT
A new reagent for the enantioselective allylation of aliphatic aldehydes has been developed. The reagent is easily prepared in a single step from commercially available materials and may be stored without significant decomposition. The reactivity of the reagent is attributed to strain-release Lewis acidity.
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Base de dados:
MEDLINE
Assunto principal:
Silanos
/
Álcoois
/
Aldeídos
Idioma:
En
Ano de publicação:
2002
Tipo de documento:
Article