Stereoselective syntheses of (+)-goniodiol, (-)-8-epigoniodiol, and (+)-9-deoxygoniopypyrone via alkoxyallylboration and ring-closing metathesis.

Ramachandran, P Veeraraghavan; Chandra, J Subash; Ram Reddy, M Venkat

Ramachandran, P Veeraraghavan; Chandra, J Subash; Ram Reddy, M Venkat.

Afiliação

Ramachandran PV; Herbert C. Brown Center for Borane Research, Department of Chemistry, Purdue University, West Lafayette, Indiana 47907-1393, USA. chandran@purdue.edu

J Org Chem ; 67(21): 7547-50, 2002 Oct 18.

Article em En | MEDLINE | ID: mdl-12375995

RESUMO

A convenient synthesis of (+)-goniodiol, (-)-8-epigoniodiol, and (+)-9-deoxygoniopypyrone has been developed via asymmetric alkoxyallylboration and ring-closing metathesis pathways.

Assuntos

Pironas/química; Pironas/síntese química; Indicadores e Reagentes; Conformação Molecular; Estereoisomerismo

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