Thioepoxide formation by ring closure of allylthiyl radicals--a novel rearrangement of allylic thionitrites.

Cavero, Marta; Motherwell, William B; Potier, Pierre; Weibel, Jean-Marc.

Afiliação

Cavero M; University College London, Christopher Ingold Laboratories, 20 Gordon Street, London, UK WC1H 0AJ.

Chem Commun (Camb) ; (20): 2394-5, 2002 Oct 21.

Article em En | MEDLINE | ID: mdl-12430457

ABSTRACT

Tertiary allylic thionitrites undergo thermal rearrangement to alpha,beta-episulfide nitroso dimers via ring closure of allylthiyl radicals.

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Base de dados: MEDLINE Idioma: En Ano de publicação: 2002 Tipo de documento: Article

Base de dados: MEDLINE Idioma: En Ano de publicação: 2002 Tipo de documento: Article