Octaethylporphyrin and expanded porphyrin complexes containing coordinated BF2 groups.
Chem Commun (Camb)
; (9): 1060-1, 2004 May 07.
Article
em En
| MEDLINE
| ID: mdl-15116184
ABSTRACT
In contrast to octaethylporphyrin, which forms a very labile bis-BF(2) complex, treatment of the hexa- and octapyrrolic expanded porphyrins amethyrin and [32]octaphyrin with BF(3).Et(2) under standard reaction and work-up conditions gives rise to stable, non-labile mono- and bis-BF(2) complexes; these were readily characterised by, inter alia, X-ray diffraction analyses.
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Base de dados:
MEDLINE
Assunto principal:
Porfirinas
/
Compostos de Boro
Idioma:
En
Ano de publicação:
2004
Tipo de documento:
Article