Synthesis and Diels-Alder reactivity of ortho-carbazolequinones.

Compain-Batissou, Muriel; Latreche, Djamila; Gentili, Jacques; Walchshofer, Nadia; Bouaziz, Zouhair

Compain-Batissou, Muriel; Latreche, Djamila; Gentili, Jacques; Walchshofer, Nadia; Bouaziz, Zouhair.

Afiliação

Compain-Batissou M; Laboratoire de Chimie Organique, Institut des Sciences Pharmaceutiques et Biologiques, Université Claude Bernard Lyon 1, 69373 Lyon cedex 08, France.

Chem Pharm Bull (Tokyo) ; 52(9): 1114-6, 2004 Sep.

Article em En | MEDLINE | ID: mdl-15340200

ABSTRACT

ABSTRACT

Oxidation of 2- and 3-hydroxycarbazoles with Frémy's salt gave the corresponding ortho-carbazolequinones. These molecules react as carbodienophiles in Diels-Alder reaction with 1-acetoxy-1,3-butadiene and 1,3-cyclopentadiene to provide the novel benzocarbazolequinone structures 15, 16, 18 and 19.

Assuntos

Carbazóis/síntese química; Quinonas/síntese química; Carbazóis/química; Modelos Químicos; Conformação Molecular; Estrutura Molecular; Quinonas/química

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