An investigation into causes and effects of high cyanide levels in the palladium-catalyzed cyanation reaction.

Marcantonio, Karen M; Frey, Lisa F; Liu, Yong; Chen, Yadan; Strine, Jeff; Phenix, Brian; Wallace, Debra J; Chen, Cheng-yi

Marcantonio, Karen M; Frey, Lisa F; Liu, Yong; Chen, Yadan; Strine, Jeff; Phenix, Brian; Wallace, Debra J; Chen, Cheng-yi.

Afiliação

Marcantonio KM; Department of Process Research, Merck Research Laboratories, P.O. Box 2000 Rahway, New Jersey 07065, USA. karen_marcantonio@merck.com

Org Lett ; 6(21): 3723-5, 2004 Oct 14.

Article em En | MEDLINE | ID: mdl-15469333

RESUMO

[reaction: see text] The palladium-catalyzed cyanation reaction is known to be sensitive to dissolved cyanide. Investigation into some causes of high levels of dissolved cyanide is presented here, along with a robust solution to this problem.

Assuntos

Cianetos/química; Paládio/química; Catálise

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Base de dados: MEDLINE Assunto principal: Paládio / Cianetos Tipo de estudo: Etiology_studies Idioma: En Ano de publicação: 2004 Tipo de documento: Article

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PubMed Links

Base de dados: MEDLINE Assunto principal: Paládio / Cianetos Tipo de estudo: Etiology_studies Idioma: En Ano de publicação: 2004 Tipo de documento: Article