One teflon-like channelled nanoporous polymer with a chiral and new uninodal 4-connected net: sorption and catalytic properties.
Chem Commun (Camb)
; (10): 1291-3, 2005 Mar 14.
Article
em En
| MEDLINE
| ID: mdl-15742055
ABSTRACT
Zn(C17H8F6O4) is the first example of a fluoro-lined nanotube organo-inorganic 3D polymeric chiral structure, which possesses two different types of isolated channels, one of them being laid out with a double spiral of CF3-groups from the ligand molecule; the structure is a new uninodal 4-connected net that only exists when bent ligands connect the centres, and the compound exhibits selective sorption and catalytic chiral recognition properties.
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Base de dados:
MEDLINE
Assunto principal:
Compostos Organometálicos
/
Polímeros
/
Zinco
/
Nanoestruturas
Idioma:
En
Ano de publicação:
2005
Tipo de documento:
Article