Feigrisolide C: structural revision and synthesis.

Kim, Woo Han; Jung, Jae Hoon; Lee, Eun

Kim, Woo Han; Jung, Jae Hoon; Lee, Eun.

Afiliação

Kim WH; Department of Chemistry, College of Natural Sciences, Seoul National University, Seoul 151-747, Korea.

J Org Chem ; 70(20): 8190-2, 2005 Sep 30.

Article em En | MEDLINE | ID: mdl-16277346

ABSTRACT

ABSTRACT

[Carbohydrate structure see text] The original macrodiolide structure proposed for feigrisolide C was incorrect. The true structure of feigrisolide C was identified as (2'S,3'S,6'R,8'R)-homononactoyl (2R,3R,6S,8S)-nonactic acid, which was confirmed by total synthesis.

Assuntos

Lactonas/química; Lactonas/síntese química; Antibacterianos/síntese química; Antibacterianos/química; Espectroscopia de Ressonância Magnética; Modelos Moleculares; Conformação Molecular; Estrutura Molecular

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