Conformational analysis of chiral helical perfluoroalkyl chains by VCD.

Monde, Kenji; Miura, Nobuaki; Hashimoto, Mai; Taniguchi, Tohru; Inabe, Tamotsu

Monde, Kenji; Miura, Nobuaki; Hashimoto, Mai; Taniguchi, Tohru; Inabe, Tamotsu.

Afiliação

Monde K; Division of Biological Sciences, Graduate School of Science, Frontier Research Center for Post-Genomic Science and Technology, Hokkaido University, Kita-ku, Sapporo 001-0021, Japan. kmonde@glyco.sci.hokudai.ac.jp

J Am Chem Soc ; 128(18): 6000-1, 2006 May 10.

Article em En | MEDLINE | ID: mdl-16669645

ABSTRACT

ABSTRACT

Vibrational circular dichroism (VCD) technique successfully revealed the absolute configuration of the biased helix of perfluoroalkyl chains in solution with the aid of theoretical calculations, which was supported by an X-ray crystallographic study.

Assuntos

Dicroísmo Circular/métodos; Fluorocarbonos/química; Cristalografia por Raios X; Glicolipídeos/química; Conformação Molecular; Espectrofotometria Infravermelho

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Base de dados: MEDLINE Assunto principal: Dicroísmo Circular / Fluorocarbonos Idioma: En Ano de publicação: 2006 Tipo de documento: Article

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XML

PubMed Links

Base de dados: MEDLINE Assunto principal: Dicroísmo Circular / Fluorocarbonos Idioma: En Ano de publicação: 2006 Tipo de documento: Article