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Stereoselective stilbene epoxidation over supported gold-based catalysts.
Lignier, Pascal; Morfin, Franck; Mangematin, Stéphane; Massin, Laurence; Rousset, Jean-Luc; Caps, Valérie.
Afiliação
  • Lignier P; Institut de Recherches sur la Catalyse (CNRS), 2 avenue Albert Einstein, 69626 Villeurbanne Cedex, France.
Chem Commun (Camb) ; (2): 186-8, 2007 Jan 14.
Article em En | MEDLINE | ID: mdl-17180241
ABSTRACT
The gold reference catalyst Au/TiO(2) exhibits high activity in the stereoselective epoxidation of trans-stilbene in methylcyclohexane in the presence of 5 mol% TBHP, by taking part in a chain reaction involving the activation of molecular oxygen by a radical produced from methylcyclohexane.
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Base de dados: MEDLINE Idioma: En Ano de publicação: 2007 Tipo de documento: Article
Buscar no Google
Base de dados: MEDLINE Idioma: En Ano de publicação: 2007 Tipo de documento: Article