Surprising role of aryl halides in nickel-catalyzed reductive aldol reactions. | Org Lett;9(3): 537-40, 2007 Feb 01. | MEDLINE

Conteúdo principal 1 Busca 2 Rodapé 3

+A A -A Alto contraste

Secretaria de Estado da Saúde - BVS

Rede de Informação e Conhecimento

Localizar descritor de assunto Busca Avançada

Surprising role of aryl halides in nickel-catalyzed reductive aldol reactions.

Chrovian, Christa C; Montgomery, John.

Afiliação

Chrovian CC; Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109-1055, USA.

Org Lett ; 9(3): 537-40, 2007 Feb 01.

Article em En | MEDLINE | ID: mdl-17249806

ABSTRACT

ABSTRACT

[reaction see text] A new nickel-catalyzed method for the reductive aldol addition of acrylates and aldehydes has been developed. An unexpected requirement for an aryl iodide additive was found in the process, and the effect was shown to be linked to an initiation step.

Buscar no Google

Base de dados: MEDLINE Idioma: En Ano de publicação: 2007 Tipo de documento: Article

Buscar no Google

Base de dados: MEDLINE Idioma: En Ano de publicação: 2007 Tipo de documento: Article