Size effect of encaged clusters on the exohedral chemistry of endohedral fullerenes: a case study on the pyrrolidino reaction of ScxGd3-xN@C80 (x = 0-3).
Org Lett
; 9(10): 2011-3, 2007 May 10.
Article
em En
| MEDLINE
| ID: mdl-17447779
ABSTRACT
We report a combined experimental and theoretical investigation on the regiochemistry of a series of TNT endohedral fullerenes ScxGd3-xN@C80 (x = 0-3) in 1,3-dipolar cycloadditions, which demonstrates that the regioselectivity of the TNT-based endohedral fullerenes ScxGd3-xN@C80 (x = 0-3) in the exohedral cycloadditions depends remarkably on the size of the encaged cluster.
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Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2007
Tipo de documento:
Article