Versatile synthesis and mechanism of activation of S-benzoxazolyl glycosides.
J Org Chem
; 72(18): 6938-46, 2007 Aug 31.
Article
em En
| MEDLINE
| ID: mdl-17676918
ABSTRACT
As a part of a program for developing new efficient procedures for stereoselective glycosylation, a range of S-benzoxazolyl (SBox) glycosides have been synthesized. The mechanistic aspects of the SBox moiety activation for glycosylation via a variety of conceptually different pathways in the presence of thiophilic, electrophilic, or metal-based promoters have been investigated.
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Benzoxazóis
/
Glicosídeos
Idioma:
En
Ano de publicação:
2007
Tipo de documento:
Article