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Rare-earth metal alkyl and hydride complexes stabilized by a cyclen-derived [NNNN] macrocyclic ancillary ligand.
Ohashi, Masato; Konkol, Marcin; Del Rosal, Iker; Poteau, Romuald; Maron, Laurent; Okuda, Jun.
Afiliação
  • Ohashi M; Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, D-52056 Aachen, Germany.
J Am Chem Soc ; 130(22): 6920-1, 2008 Jun 04.
Article em En | MEDLINE | ID: mdl-18461944
ABSTRACT
A trinuclear rare-earth metal hydride complex was synthesized from the dialkyl complex supported by a monoanionic [NNNN] macrocycle and shown to catalyze the hydrosilylation of olefins efficiently.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2008 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2008 Tipo de documento: Article