Study of the influence of location of substitutions on the surface energy of dioctahedral smectites.
J Colloid Interface Sci
; 325(1): 275-81, 2008 Sep 01.
Article
em En
| MEDLINE
| ID: mdl-18597771
ABSTRACT
The surface energy of some clays belonging to the smectite group has been calculated starting from crystal structures and combining a partial charge model with the computation of the lattice energy. The dioctahedral smectites studied here include montmorillonite; beidellites; and nontronite. One of the differences between these clays is the location of the substitution in the octahedral sheet or in the tetrahedral one. Another is the possibility of vacancies in cis- or trans-octahedral positions. These locations and vacancies have an effect on the distortion of the crystal framework and therefore on the surface energy. Calculated surface energies of the solid samples increase in the order beidellites > montmorillonite > nontronite. The bond energy between the interlayer cation and the layer appears to follow the same order and to depend both on the nature of the most electropositive elements of the layer and on their location. The trends obtained provide elements for an analysis of data related to interlayer enlargement.
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MEDLINE
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En
Ano de publicação:
2008
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Article