Dissociative solvolytic cleavage of methyl (ortho-carboxymethyl)aryl phosphate diesters mediated by Yb3+ in methanol gives a 10(12)-fold rate acceleration attributable to leaving group assistance.
J Am Chem Soc
; 131(1): 368-77, 2009 Jan 14.
Article
em En
| MEDLINE
| ID: mdl-19055404
Assuntos
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Organofosfatos
/
Itérbio
/
Benzoatos
Idioma:
En
Ano de publicação:
2009
Tipo de documento:
Article