Syntheses, structural studies, photoelectron spectra and density functional theory calculations of the "pseudo" tetraphospha-metallocenes [M(eta-P2C3Bu(t)3)(2)], (M = Ni, Pd, Pt).
Dalton Trans
; (7): 1164-71, 2009 Feb 21.
Article
em En
| MEDLINE
| ID: mdl-19322487
ABSTRACT
Syntheses and structural characterization of the complexes [M(eta-P(2)C(3)Bu(t)(3))(2)], (M = Ni, Pd, Pt) are described. The nickel compound has an 18-electron [Ni(eta(5)-P(2)C(3)Bu(t)(3))(eta(3)-P(2)C(3)Bu(t)(3))] structure, whereas the palladium and platinum compounds both have a 16-electron [M(eta(3)-P(2)C(3)Bu(t)(3))(2)] structure (M = Pd, Pt).The electronic structure is examined and discussed using both photoelectron spectroscopy and DFT calculations.
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MEDLINE
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Ano de publicação:
2009
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Article