One-step synthesis of fullerene hydride C(60)H2 via hydrolysis of acylated fullerenes.
J Org Chem
; 74(15): 5746-9, 2009 Aug 07.
Article
em En
| MEDLINE
| ID: mdl-19572499
ABSTRACT
The hitherto unexplored class of acylated fullerene compounds has been shown to be excellent C(60)H2 precursors. Upon a simple treatment with basic Al2O3, they are hydrolyzed quantitatively into C(60)H2. This key feature led to the development of a new, straightforward protocol for the selective synthesis of the simplest [60]fullerene hydride, C(60)H2. This protocol may offer an advantageous alternative to previously known methods for the synthesis of C(60)H2 allowing for a rapid access to C(60)H2 in good yield and high purity without tedious separating processes.
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Fulerenos
/
Óxido de Alumínio
/
Hidrogênio
Tipo de estudo:
Guideline
Idioma:
En
Ano de publicação:
2009
Tipo de documento:
Article