Russian-doll-type metal carbide endofullerene: synthesis, isolation, and characterization of Sc4C2@C80.
J Am Chem Soc
; 131(46): 16646-7, 2009 Nov 25.
Article
em En
| MEDLINE
| ID: mdl-19877678
ABSTRACT
For the first time, we have produced the stable compound Sc(4)C(2)@C(80)-I(h) and characterized it as a metal carbide endofullerene by FTIR and Raman spectroscopies in combination with DFT calculations. Furthermore, DFT calculations have demonstrated that this molecule has a Russian-doll-type structure, C(2)@Sc(4)@C(80).
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MEDLINE
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En
Ano de publicação:
2009
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Article