A metal-organic framework with a covalently prefabricated porous organic linker.

Swamy, Shashikala I; Bacsa, John; Jones, James T A; Stylianou, Kyriakos C; Steiner, Alexander; Ritchie, Lyndsey K; Hasell, Tom; Gould, Jamie A; Laybourn, Andrea; Khimyak, Yaroslav Z; Adams, Dave J; Rosseinsky, Matthew J; Cooper, Andrew I

Swamy, Shashikala I; Bacsa, John; Jones, James T A; Stylianou, Kyriakos C; Steiner, Alexander; Ritchie, Lyndsey K; Hasell, Tom; Gould, Jamie A; Laybourn, Andrea; Khimyak, Yaroslav Z; Adams, Dave J; Rosseinsky, Matthew J; Cooper, Andrew I.

Afiliação

Swamy SI; Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool L69 7ZD, United Kingdom.

J Am Chem Soc ; 132(37): 12773-5, 2010 Sep 22.

Article em En | MEDLINE | ID: mdl-20795723

RESUMO

We report here the synthesis of a metal-organic framework comprising an organic cage linker with covalently prefabricated, intrinsic porosity. The network can be compared to a porous rock salt structure where the pores are partially filled by charge-balancing cations.

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2010 Tipo de documento: Article

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2010 Tipo de documento: Article