Expeditious synthesis of phenanthridines from benzylamines via dual palladium catalysis.
Org Lett
; 12(24): 5692-5, 2010 Dec 17.
Article
em En
| MEDLINE
| ID: mdl-21082784
ABSTRACT
A method for the synthesis of phenanthridines from benzylamines and aryl iodides which uses a dual palladium-catalyzed process is developed. The domino sequence ends via an intramolecular amination and an oxidative dehydrogenation. No protecting group or prefunctionalization of the amine is required, and the process uses dioxygen as the terminal oxidant.
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MEDLINE
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En
Ano de publicação:
2010
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Article