Dichloridobis(methyl-amine-κN)boron(III) chloride.
Acta Crystallogr Sect E Struct Rep Online
; 64(Pt 3): o583, 2008 Feb 13.
Article
em En
| MEDLINE
| ID: mdl-21201922
ABSTRACT
The title compound, C(2)H(10)BCl(2)N(2) (+)·Cl(-) or [BCl(2)(H(3)CNH(2))(2)](+)·Cl(-), is the first crystallographically characterized di(alkyl-amine)-BCl(2) (+) salt. The B atom is tetra-hedrally coordinated by two Cl and two methyl-amine N atoms. In the crystal structure, the cations and anions inter-act via N-Hâ¯Cl hydrogen bonds (mean Hâ¯Cl = 2.40â
Å), resulting in a layered structure.
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MEDLINE
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En
Ano de publicação:
2008
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Article