Iodidotris(triphenyl-phosphine)copper(I) acetonitrile solvate.
Acta Crystallogr Sect E Struct Rep Online
; 64(Pt 4): m577, 2008 Mar 29.
Article
em En
| MEDLINE
| ID: mdl-21202027
ABSTRACT
The title compound, [CuI(C(18)H(15)P)(3)]·C(2)H(3)N, was obtained from the reaction of triphenyl-phosphine and copper(I) iodide in acetonitrile. The monomeric form of the complex has slightly distorted coordination of Cu by the I atom and three P atoms. The crystal structure is stabilized by C-Hâ¯π inter-actions between phenyl H atoms and phenyl rings. In addition, the complex mol-ecules exhibit C-Hâ¯N hydrogen bonds between phenyl H atoms and acetonitrile N atoms. The crystal used was an inversion twin, with nearly equal component populations of 0.522â
(8) and 0.478â
(8).
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MEDLINE
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En
Ano de publicação:
2008
Tipo de documento:
Article