[Spectroscopic properties of Er3+ : Ba0.65Sr0.35TiO nanopowders].
Guang Pu Xue Yu Guang Pu Fen Xi
; 30(11): 3107-10, 2010 Nov.
Article
em Zh
| MEDLINE
| ID: mdl-21284193
ABSTRACT
Ba0.65Sr0.35TiO2 (BST) nanopowders doped with Er3+ were prepared by sol-gel method. The absorption spectrum and photoluminescence (PL) spectrum of Er3+ BST nanopowders was measured at room temperature. Based on the Judd-Ofelt theory, the intensity parameters of Er3+ in BST nanopowders were determined, omega2 = 0.993 x 10(-20) cm2, omega4 = 1.665 x 10(-20) cm2 and omega = 0.540 x 10(-20) cm2, and then the values of the line strengths, radiative transition probabilities and branching ratios of Er3+ were calculated. According to the PL spectrum, the emission bands centered at about 522, 545, 654 and 851 nm corresponding to 2H(11/2)-->4S(3/2-->4I(15/2), 4F(9/2)-->4I(15/2), and 4S(3/2-->4I(13/2) transition were observed, and the emission properties were also discussed. The results show that the Er3+ BST nanomaterials are prospective candidates for applications in new photoelectric devices.
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Base de dados:
MEDLINE
Idioma:
Zh
Ano de publicação:
2010
Tipo de documento:
Article