catena-Poly[[aqua-(5,5'-dimethyl-2,2'-bipyridine-κN,N')copper(II)]-µ-2,2'-oxydibenzoato-κO:O'].
Acta Crystallogr Sect E Struct Rep Online
; 66(Pt 8): m905-6, 2010 Jul 10.
Article
em En
| MEDLINE
| ID: mdl-21588146
ABSTRACT
In the title compound, [Cu(C(14)H(8)O(5))(C(12)H(12)N(2))(H(2)O)](n), the Cu(II) ion is penta-coordinated in a square-pyramidal geometry. Two N atoms of the chelating 5,5'-dimethyl-2,2'-bipyridine (dbp) ligand and two O atoms of two different 2,2'-oxydibenzoic (odb) ligands occupy the basal plane while the water O atom completes the square-pyramidal geometry at the apical site. The non-water N(2)O(2) donor atoms are nearly coplanar, with a mean deviation from the least-squares plane of 0.0518â
(11)â
Å and the Cu atom is displaced by 0.1507â
(11)â
Å from this plane towards the apical water O atom. Further coordination via the 2,2'-oxydibenzoate anions forms a one-dimensional coordination polymer extending parallel to [010]. In the crystal structure, O-Hâ¯O hydrogen bonds link the mol-ecules into a two-dimensional supra-molecular structure.
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Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2010
Tipo de documento:
Article