Bis[2-(methyl-amino)-troponato]copper(II).
Acta Crystallogr Sect E Struct Rep Online
; 66(Pt 12): m1508, 2010 Nov 06.
Article
em En
| MEDLINE
| ID: mdl-21589214
ABSTRACT
In the title compound, [Cu(C(8)H(8)NO)(2)], a strictly square-planar geometry about the Cu(II) metal atom is observed. Substitution of an O atom with a methyl-functionalized N atom does not significantly alter the bond distances and angles in the copper(II) complex when compared with a similar bis-(troponato)copper(II) complex. π-π stacking is observed between the tropolone rings, with inter-planar distances of 3.5039â
(16) and 3.2933â
(15)â
Å, respectively. Additional stabilisation of the structure is accomplished through C-Hâ¯O hydrogen-bonding interactions.
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MEDLINE
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En
Ano de publicação:
2010
Tipo de documento:
Article