(N-Butyl-N-phenyl-dithio-carbamato-κS)triphenyl-tin(IV).
Acta Crystallogr Sect E Struct Rep Online
; 67(Pt 5): m555-6, 2011 May 01.
Article
em En
| MEDLINE
| ID: mdl-21754289
The title compound, [Sn(C(6)H(5))(3)(C(11)H(14)NS(2))], features a tetra-hedrally coordinated Sn atom, as the dithio-carbamate ligand coordinates in a monodentate fashion. Due to the proximity of the non-coordinating thione S atom, distortions from ideal tetra-hedral geometry about the metal atom are evident with the widest C-Sn-S angle being 117.26â
(5)°. In the crystal, mol-ecules are linked by C-Hâ¯S inter-actions, which generate helical supra-molecular chains along the b axis.
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2011
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Article