Transient innermolecular carbene-hemicarcerand complex of fluorophenylcarbene.
J Phys Chem A
; 115(47): 13799-803, 2011 Dec 01.
Article
em En
| MEDLINE
| ID: mdl-22050236
ABSTRACT
Laser flash photolysis of fluorophenyldiazirine incarcerated in hemicarcerand 2 affords incarcerated fluorophenylcarbene [2â3], which forms a metastable, innermolecular π-complex with aryl moieties of 2. This carbene complex can be observed spectroscopically. Extensive computational studies provide insights into the structure, spectroscopy, energetics, and kinetics of the 2â3 carbene complex.
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Hidrocarbonetos Aromáticos com Pontes
/
Metano
Idioma:
En
Ano de publicação:
2011
Tipo de documento:
Article