catena-Poly[(µ-2-amino-1,3,4-thia-diazole-κN:N)di-µ-chlorido-cadmium].
Acta Crystallogr Sect E Struct Rep Online
; 67(Pt 8): m1082, 2011 Aug 01.
Article
em En
| MEDLINE
| ID: mdl-22090859
ABSTRACT
In the title coordination polymer, [CdCl(2)(C(2)H(3)N(3)S)](n), the Cd(II) cation is coordinated by four Cl(-) anions and two N atoms from two trans 2-amino-1,3,4-thia-diazole (L) ligands in a distorted octa-hedral geometry. The L ligand and Cl(-) anions bridge adjacent Cd cations, forming a polymeric chain along the b axis; the separation between adjacent Cd cations is 3.619â
(1)â
Å. In the crystal, the polymeric chains are inter-linking through N-Hâ¯Cl hydrogen bonds between the L ligands and Cl(-) anions.
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MEDLINE
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En
Ano de publicação:
2011
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Article