Poly[bis-[µ-1,4-bis-(imidazol-1-ylmeth-yl)benzene]-dichloridomanganese(II)].
Acta Crystallogr Sect E Struct Rep Online
; 67(Pt 8): m1156, 2011 Aug 01.
Article
em En
| MEDLINE
| ID: mdl-22090913
ABSTRACT
In the crystal structure of the title compound, [MnCl(2)(C(14)H(14)N(4))(2)](n), the Mn(II) atom, lying on an inversion center, is coordinated by four N atoms from four 1,4-bis-(imidazol-1-ylmeth-yl)benzene (bimb) ligands and two Cl(-) anions in a distorted octa-hedral geometry. The bimb ligands bridge the Mn(II) atoms, forming a two-dimensional polymeric complex, which is composed of a 52-membered [Mn(4)(bimb)(4)] ring with distances of 7.7812â
(2) and 27.4731â
(9)â
Å between opposite metal atoms. Weak C-Hâ¯π inter-actions are present in the crystal structure.
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MEDLINE
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En
Ano de publicação:
2011
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Article