1-(2,4-Dichloro-benz-yl)pyridinium bis-(2-sulfanyl-idene-1,3-dithiole-4,5-dithiol-ato-κS,S')nickelate(III).
Acta Crystallogr Sect E Struct Rep Online
; 67(Pt 12): m1654, 2011 Dec 01.
Article
em En
| MEDLINE
| ID: mdl-22199481
In the title compound, (C(12)H(10)Cl(2)N)[Ni(C(3)S(5))(2)], the Ni(III) atom is chelated by two bidentate 2-sulfanyl-idene-1,3-dithiole-4,5-dithiol-ate (dmit) dianions and shows a distorted square-planar geometry. The two dmit ligands are twisted with respect to each other by 3.21â
(2)°. In the cation, the two aromatic groups linked by the methyl-ene bridging group form a dihedral angle of 68.09â
(2)°. Sâ¯S [3.6212â
(11) and 3.5573â
(9)â
Å] and Niâ¯S [3.566â
(2)Å] inter-actions influence the arrangement of the anions in the crystal.
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2011
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Article