1-(4-Iodo-benz-yl)-3-methyl-pyridinium bis-(benzene-1,2-dithiol-ato)nickelate(III).
Acta Crystallogr Sect E Struct Rep Online
; 67(Pt 11): m1607, 2011 Nov.
Article
em En
| MEDLINE
| ID: mdl-22219834
ABSTRACT
The asymmetric unit of the title compound, (C(13)H(13)IN)[Ni(C(6)H(4)S(2))(2)], contains half each of two centrosymmetric anions and a single cation in a general position. In the anions, the Ni(III) ions are surrounded by four S atoms in a distorted square-planar geometry. In the crystal, the anions exhibit two different packing modes by stacking along the a axis in face-to-face and side-by-side fashions. Inter-ionic C-Hâ¯S hydrogen bonds and π-π stacking inter-actions [centroid-centroid distance = 3.6947â
(5)â
Å] are observed.
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MEDLINE
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En
Ano de publicação:
2011
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Article