catena-Poly[[[bis-(nitrato-κO)copper(II)]-bis-[µ-1,3-bis-(imidazol-1-yl)-5-methyl-benzene-κ(2)N(3):N(3')]] dihydrate].
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 6): m840, 2012 Jun 01.
Article
em En
| MEDLINE
| ID: mdl-22719378
In the title complex, {[Cu(NO(3))(2)(C(13)H(12)N(4))(2)]·2H(2)O}(n), the Cu(II) atom is located on a crystallographic center of symmetry and adopts an N(4)O(2) octa-hedral coordination geometry with four imidazole N atoms in the equatorial sites and two O atoms in the axial sites. The dihedral angles between the central benzene ring and the imidazole rings are 4.93â
(11) and 46.08â
(12)°. The 1,3-bis-(imidazol-1-yl)-5-methyl-benzene ligand is bis-monodentate, linking symmetry-related Cu(II) atoms into sheets in the bc plane. These sheets are further bridged into a three-dimensional supra-molecular structure by O-Hâ¯O and C-Hâ¯O hydrogen bonds.
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Ano de publicação:
2012
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Article