Method for synthesis of tetrabenzoporphyrin precursor for use in organic electronic devices.
J Org Chem
; 77(18): 8329-31, 2012 Sep 21.
Article
em En
| MEDLINE
| ID: mdl-22900882
ABSTRACT
We developed a new synthetic method for bicyclo[2.2.2]octadiene (BCOD)-fused porphyrin (1), a tetrabenzoporphyrin (TBP, 2) precursor that is well-known as a good material for use in organic electronic devices. The newly developed method synthesizes the BCOD-fused pyrrole intermediate (which is the most important intermediate in synthesizing BCOD-fused porphyrin) in a simpler and easier manner than other existing methods, and thus, the new method can efficiently synthesize the TBP precursor.
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Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2012
Tipo de documento:
Article