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nBu4NI-catalyzed direct synthesis of α-ketoamides from aryl methyl ketones with dialkylformamides in water using TBHP as oxidant.
Mai, Wen-Peng; Wang, Hui-Hui; Li, Zhi-Cheng; Yuan, Jin-Wei; Xiao, Yong-Mei; Yang, Liang-Ru; Mao, Pu; Qu, Ling-Bo.
Afiliação
  • Mai WP; School of Chemistry and Chemical Engineering, Henan University of Technology, Lianhua Street, Zhengzhou, 450001, PR China. maiwp@yahoo.com
Chem Commun (Camb) ; 48(81): 10117-9, 2012 Oct 18.
Article em En | MEDLINE | ID: mdl-22951489
ABSTRACT
A novel and easy practical direct synthesis of α-ketoamides has been developed without metals in water. This procedure was catalyzed by nBu(4)NI using TBHP as oxidant from simple substrates, aryl methyl ketones and dialkylformamides.
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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Oxidantes / Terc-Butil Hidroperóxido / Formamidas / Amidas / Cetonas Idioma: En Ano de publicação: 2012 Tipo de documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Assunto principal: Oxidantes / Terc-Butil Hidroperóxido / Formamidas / Amidas / Cetonas Idioma: En Ano de publicação: 2012 Tipo de documento: Article