Europium pyrimidine-4,6-dicarboxylate framework with a single-crystal-to-single-crystal transition and a reversible dehydration/rehydration process.
Inorg Chem
; 52(7): 3582-4, 2013 Apr 01.
Article
em En
| MEDLINE
| ID: mdl-23485331
ABSTRACT
In this paper, a novel three-dimensional (3D) porous lanthanide-organic framework, Eu2(µ4-pmdc)2(OH)2·3H2O (1), which is stable up to 400 °C, has been hydrothermally synthesized and characterized. It shows intriguing single-crystal-to-single-crystal transformation and reversible dehydration/rehydration phenomenon upon removal and rebinding of the lattice water molecules, which is supported by single-crystal X-ray diffraction, powder X-ray diffraction, and photoluminescence data.
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Pirimidinas
/
Ácidos Carboxílicos
/
Água
/
Európio
Idioma:
En
Ano de publicação:
2013
Tipo de documento:
Article