(4,6-Dimethyl-2-sulfanylidenepyrimidin-1-ium) trichlorido(thiourea-κS)zinc(II).
Acta Crystallogr C
; 69(Pt 4): 384-7, 2013 Apr.
Article
em En
| MEDLINE
| ID: mdl-23579712
ABSTRACT
The title compound, (C6H9N2S)[ZnCl3{SC(NH2)2}], exists as a zincate where the zinc(II) centre is coordinated by three chloride ligands and a thiourea ligand to form the anion. The organic cation adopts the protonated 4,6-dimethyl-2-sulfanylidenepyrimidin-1-ium (L) form of 4,6-dimethylpyrimidine-2(1H)-thione. Two short N-H···Cl hydrogen bonds involving the pyrimidine H atoms and the [ZnCl3L](-) anion form a crystallographically centrosymmetric dimeric unit consisting of two anions and two cations. The packing structure is completed by longer-range hydrogen bonds donated by the thiourea NH2 groups to chloride ligand hydrogen-bond acceptors.
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MEDLINE
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En
Ano de publicação:
2013
Tipo de documento:
Article