Polypeptoid brushes by surface-initiated polymerization of N-substituted glycine N-carboxyanhydrides.
Langmuir
; 29(23): 6983-8, 2013 Jun 11.
Article
em En
| MEDLINE
| ID: mdl-23663172
ABSTRACT
Polypeptoid brushes were synthesized by surface-initiated polymerization of N-substituted glycine N-carboxyanhydrides on self-assembled amine monolayers. Using the presented grafting-from approach, polypeptoid brush thicknesses of approximately 40 nm could be obtained as compared to previously reported brush thicknesses of 4 nm. Moreover, hydrophilic, hydrophobic and amphiphilic polymer brushes were realized which are expected to have valuable applications as nonfouling surfaces and as model or references systems for surface grafted polypeptides.
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Glicinas N-Substituídas
/
Peptoides
/
Anidridos
Idioma:
En
Ano de publicação:
2013
Tipo de documento:
Article