Copper-promoted Sandmeyer trifluoromethylation reaction.
J Am Chem Soc
; 135(23): 8436-9, 2013 Jun 12.
Article
em En
| MEDLINE
| ID: mdl-23718557
ABSTRACT
A copper-promoted trifluoromethylation reaction of aromatic amines is described. This transformation proceeds smoothly under mild conditions and exhibits good tolerance of many synthetically relevant functional groups. It provides an alternative approach for the synthesis of trifluoromethylated arenes and heteroarenes. It also constitutes a new example of the Sandmeyer reaction.
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Cobre
/
Aminas
/
Hidrocarbonetos Fluorados
Idioma:
En
Ano de publicação:
2013
Tipo de documento:
Article