Synthesis of highly cis, syndiotactic polymers via ring-opening metathesis polymerization using ruthenium metathesis catalysts.
J Am Chem Soc
; 135(27): 10032-5, 2013 Jul 10.
Article
em En
| MEDLINE
| ID: mdl-23782172
ABSTRACT
The first example of ruthenium-mediated ring-opening metathesis polymerization generating highly cis, highly tactic polymers is reported. While the cis content varied from 62 to >95% depending on the monomer structure, many of the polymers synthesized displayed high tacticity (>95%). Polymerization of an enantiomerically pure 2,3-dicarboalkoxynorbornadiene revealed a syndiotactic microstructure.
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Compostos Organometálicos
/
Polímeros
/
Rutênio
Idioma:
En
Ano de publicação:
2013
Tipo de documento:
Article