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Pd(II)-catalyzed direct C-H acylation of N-Boc hydrazones with aldehydes: one-pot synthesis of 1,2-diacylbenzenes.
Sharma, Satyasheel; Kim, Aejin; Park, Jihye; Kim, Mirim; Kwak, Jong Hwan; Jung, Young Hoon; Park, Jung Su; Kim, In Su.
Afiliação
  • Sharma S; School of Pharmacy, Sungkyunkwan University, Suwon 440-746, Republic of Korea. insukim@skku.edu.
Org Biomol Chem ; 11(45): 7869-76, 2013 Dec 07.
Article em En | MEDLINE | ID: mdl-24129548
A palladium(II)-catalyzed direct acylation of acetophenone N-Boc hydrazones with aldehydes via C-H bond activation is described. This protocol provides direct access to a range of 1,2-diacylbenzenes, which are useful precursors to construct biologically interesting and pharmaceutically important compounds.
Assuntos

Texto completo: 1 Base de dados: MEDLINE Assunto principal: Compostos Organometálicos / Paládio / Benzofenonas / Aldeídos / Hidrazonas Idioma: En Ano de publicação: 2013 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Assunto principal: Compostos Organometálicos / Paládio / Benzofenonas / Aldeídos / Hidrazonas Idioma: En Ano de publicação: 2013 Tipo de documento: Article