Synthesis of benzocyclohepta[b]indoles by Lewis acid catalyzed annulation of two 3-(1H-isochromen-1-yl)-1H-indoles.
J Org Chem
; 79(2): 686-91, 2014 Jan 17.
Article
em En
| MEDLINE
| ID: mdl-24369039
ABSTRACT
A novel Lewis acid catalyzed annulation reaction has been established for the synthesis of benzocyclohepta[b]indoles. This method represents a new annulation strategy to a seven-membered carbocyclic ring system from two 3-(1H-isochromen-1-yl)-1H-indole molecules using Cu(OTf)2 catalyst; moreover, the products, benzocyclohepta[b]indoles, can be used as the rapid mercuric ion colorimetric detection reagents.
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Cromanos
/
Mesilatos
/
Cicloeptanos
/
Ácidos de Lewis
/
Indóis
Idioma:
En
Ano de publicação:
2014
Tipo de documento:
Article