A copper complex supported by an N2S-tridentate ligand inducing efficient heterolytic O-O bond cleavage of alkylhydroperoxide.
Dalton Trans
; 43(12): 4871-7, 2014 Mar 28.
Article
em En
| MEDLINE
| ID: mdl-24492382
ABSTRACT
We have recently reported a copper(II)-superoxide complex supported by an N3-tridentate ligand (L(N3)), which exhibits a similar structure and reactivity to those of a putative reactive intermediate involved in the catalytic reactions of copper monooxygenases such as peptidylglycine α-hydroxylating monooxygenase (PHM) and dopamine ß-monooxygenase (DßM). In this study, we have synthesised and characterised copper complexes supported by a related sulphur-containing ligand (L(N2S)) to get insight into the notable electronic effect of the sulphur donor atom in the reaction with cumene hydroperoxide, inducing efficient heterolytic O-O bond cleavage.
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Base de dados:
MEDLINE
Assunto principal:
Sulfetos
/
Derivados de Benzeno
/
Cobre
/
Complexos de Coordenação
Idioma:
En
Ano de publicação:
2014
Tipo de documento:
Article