A highly stable MOF with a rod SBU and a tetracarboxylate linker: unusual topology and CO2 adsorption behaviour under ambient conditions.
Chem Commun (Camb)
; 50(31): 4047-9, 2014 Apr 21.
Article
em En
| MEDLINE
| ID: mdl-24608436
ABSTRACT
A Mn-based rod metal-organic framework (MOF), ROD-6, with a new lrk net is synthesized. It represents an unusual type of MOF topology containing both a 1-periodic secondary building unit (rod SBU) and a polytopic linker (here 1,3,6,8-tetrakis(p-benzoic acid)pyrene), and also exhibits high stability (up to 485 °C) and unusual CO2 uptake behaviour and selectivity despite the lack of strong interacting sites, demonstrated by the low and increasing heat of adsorption.
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Base de dados:
MEDLINE
Assunto principal:
Compostos Organometálicos
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Dióxido de Carbono
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Poluentes Atmosféricos
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Manganês
Idioma:
En
Ano de publicação:
2014
Tipo de documento:
Article