Stepwise assembly of Pd(6)(RuL(3))(8) nanoscale rhombododecahedral metal-organic cages via metalloligand strategy for guest trapping and protection.

Li, Kang; Zhang, Lu-Yin; Yan, Cheng; Wei, Shi-Chao; Pan, Mei; Zhang, Li; Su, Cheng-Yong

Li, Kang; Zhang, Lu-Yin; Yan, Cheng; Wei, Shi-Chao; Pan, Mei; Zhang, Li; Su, Cheng-Yong.

Afiliação

Li K; MOE Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, Lehn Institute of Functional Materials, School of Chemistry and Chemical Engineering, Sun Yat-Sen University , Guangzhou 510275, China.

J Am Chem Soc ; 136(12): 4456-9, 2014 Mar 26.

Article em En | MEDLINE | ID: mdl-24611560

ABSTRACT

ABSTRACT

Stepwise synthesis of nanosized Pd-Ru heteronuclear metal-organic cages from predesigned redox- and photo-active Ru(II)-metalloligand and naked Pd(II) ion is described. The resulting cage shows rhombododecahedral shape and contains a 5350 Å(3) cavity and 12 open windows, facilitating effective trapping of both polar and nonpolar guest molecules. Protection of photosensitive guests against UV radiation is studied.

Assuntos

Compostos Organometálicos/química; Paládio/química; Interações Hidrofóbicas e Hidrofílicas; Ligantes; Conformação Molecular; Simulação de Dinâmica Molecular

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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Compostos Organometálicos / Paládio Idioma: En Ano de publicação: 2014 Tipo de documento: Article

Texto completo

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XML

PubMed Links

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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Compostos Organometálicos / Paládio Idioma: En Ano de publicação: 2014 Tipo de documento: Article